Material safety data sheet methyl tertbutyl ether mtbe msds no. Material safety data sheet effective date 012420 according to osha hazard communication standard, 29 cfr 1910. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. It has a minty smell, vaguely reminiscent of diethyl ether, leading to unpleasant taste and odor in water. The collections of msdss listed are for commercially available products for a number of exxonmobil companies and their affiliates. Combination of sulfuric acid modified bagasse activated carbonbone biochar beads and acinetobacter indicus screened from petroleum contaminated soil was the best condition for gaseous methyl tertbutyl ether mtbe removal. It was found that h 2 so 4 modified bagasse ac in powder form had higher adsorption capacity 989. Material safety data sheet gasoline, all grades msds no. Four charcoal tubes spiked with 415 g mtbe in gasoline had air drawn for six hours at 100 mlmin and then were stored at 7 c for five days indicating 103. Mtbe increases octane and oxygen levels in gasoline and reduces pollution emissions. However, the information is provided without any warranty or guarantee, express or implied, regarding its correctness. Degradation of methyl tertiarybutyl ether mtbe by anodic. Mtbe methyltertbutyl ether is reported to metabolize to tertbutyl alcohol and formaldehyde by microsomal demethylation, mtbe methyltertbutyl ether should be considered a. Bioremediation of gaseous methyl tertbutyl ether by.
Most of the mtbe that you breathe in or take in by mouth can get into your blood. Identification of the substancemixture and of the companyundertaking 1. Ethanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory animals. If your skin comes into contact with mtbe, it can enter your body through the skin, but this happens more slowly. Methyl tertbutyl ether mtbe is a flammable liquid with a distinctive, disagreeable odor. Constituent of concern methyl tertiarybutyl ether mtbe aliases mtbe, methyl tertbutyl ether, 2methoxy2methyl propane, methyl 1,1dimethylethyl ether chemical formula c 5 h 12 o or ch 3 3 coch 3 cas no. Groundwater information sheet methyl tertiarybutyl. Conventional gasoline and rbob do not have oxygenates ethanol or mtbe andor tame. Mtbe production material balance project you manage a chemical plant within a refinery complex that produces 60,000 tonney of methyl tertiarybutyl ether mtbe. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa. Mtbe is produced in very large quantities over 200,000 barrels per day in the u. Mtbe safety data sheet product name conforms to regulation ec no. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database.
It is one of a group of chemicals commonly known as. Mtbe methyl tertiarybutyl ether is a chemical compound that is manufactured by the chemical reaction of methanol and isobutylene. Coch find msds or sds, a coa, data sheets and more information. Etbe has a lower reid vapor pressure rvp and higher octane index than mtbe. The catalytic results are correlated with the surface. Mtbe synthesis from tertbutyl alcohol tba and methanol has been studied using beta zeolites. Because of concerns for groundwater contamination and water quality, mtbe is now banned or limited in. Subsequent revisions to california state legislation has seen the phaseout of mtbe, and a tightening of construction and. Unlike ethanol, mtbe does not increases evaporative emissions from gasoline and is fully fungible in existing gasoline distribution systems. Keep away from heat, hot surfaces, sparks, open flames and other.
First aid measures eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Methyl tertbutyl ether mtbe methyl tertbutyl ether mtbe is a flammable liquid that has been used as an additive for unleaded gasoline since the 1980s. Material safety data sheet gasoline, all grades msds. Biorem2000 oil digestant mtbe material safety data sheet the information provided in this msds is believed to be reliable and accurate. Methyl tertbutyl ether safety data sheet according to federal register vol. Identification of the substancepreparation and of the companyundertaking product name phenol unid no un1671 synonyms phenol molecular weight 94. It has weak aesthetic properties, and prolonged exposure to high concentrations may cause signs or symptoms of cns depression. Chemical product and company identification product name. Mtbe is mainly a component in gasoline enhancing octane properties.
Although hydrolysis in the presence of strong acids has been recognized as a mechanism for mtbe transformation, it has been discounted as a significant reaction under environmental. Do not allow contact with soil, surface or ground water. Methyl tertbutyl ether an overview sciencedirect topics. Box 2650 tulsa, oklahoma 74101 for emergency source information contact. Synthesis of methyl tertbutyl ether from tertbutyl. Methyl tertbutyl ether mtbe, also known as tertbutyl methyl ether, is an organic compound with a structural formula ch 3 3 coch 3. When chemicals like mtbe are added to gasoline, engines produce less carbon monoxide and other carboncontaining air pollutants by burning this reformulated gasoline. Groundwater information sheet methyl tertiarybutyl ether mtbe. Butyl ether mtbe substance namesubstance name methyltertbutyl ether mtbe. Atsdr toxic substances methyl tertbutyl ether mtbe.
Mtbe is a blending component of gasoline, used as an oxygenate to. Biorem2000 oil digestant mtbe material safety data sheet. Mtbe is a gasoline additive used to increase octane number that is produced from methanol and isobutylene. Hydrolysis of tertbutyl methyl ether mtbe in dilute. Mtbe and the requirements for underground storage tank. The conditions or methods of handling, storage, use and disposal of the product are. Mtbe is a common component in reformulated fuels developed to reduce smog and meet the goals of the clean air act. Methyl tertbutyl ether mtbe is a mucosal and eye irritant. In the unlikely event of ingestion of mtbe, appropriate lavage procedures should be considered to avoid accidental aspiration of the product. Methanol is purchased but the isobutylene is obtained from a refinery stream. Methyl tertiary butyl ether mtbe is used as a highoctane additive component that helps gasoline burn cleaner and reduces automobile emissions. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. Safety data sheet according to federal register vol. From this site, you can search, view, print and download msdss for selected exxon, esso and mobil products.
Increasing the reaction temperature results in an increase of tba conversion with concomittant decrease of mtbe selectivity. Cas 1634044, ec number 2166531, chemical formula ch. Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations that have collectively been termed the fetal alcohol syndrome. Ensure that medical personnel are aware of the materials involved, and take precautions to protect themselves. Bst was establishedin 1991 as a pioneer of c4 business in thailand from mixed c4 feedstock supply by olefins plants, under thesecond stage of the national petrochemical industrial development program initiated by the thai government. Mtbe has been produced in very large quantities for use as a gasoline additive since about 1979. The results demonstrate that mtbe is sensitive to acidcatalyzed hydrolysis reaction that generates tertbutyl alcohol tba and methanol as products. Patients treated in this way have mtbe delivered directly to their gall bladders. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone.
In order to access the atsdr toxicological profiles pdf files below, you must have adobe acrobat reader. This lack of reactivity has led to concerns of the longterm impacts of mtbe in groundwater. Methyl tertbutyl ether mtbe is manufactured by the chemical reaction of methanol and isobutene for primary use in gasoline 59. Mtbe is a volatile, flammable, and colorless liquid that is sparingly soluble in water. Methanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory animals. Methyl tertbutyl ether mtbe wisconsin department of. The reaction is firstorder with respect to the concentration of mtbe and hydronium ion with a secondorder rate constant of about 0. Welcome to the material safety data sheet worldwide repository. Extremely flammable eye and mucous membrane irritant effects central nervous system harmful or fatal if swallowed aspiration hazard high fire hazard. Degradation of methyl tertiarybutyl ether mtbe by anodic fenton treatment article in journal of hazardous materials 14412. Methyl tertbutyl ether recommended use laboratory chemicals. In order to meet the needs of our customers, lyondellbasells product line now includes gasoline grade methyl tertiary butyl ether mtbe, and ethyl tertiary butyl ether etbe.
First aid measures description of first aid measures. Hold eyelids apart and flush eyes with plenty of water for at least 20 minutes. Methyl tbutyl ether, mtbe, tertbutyl methyl ether, 2methoxy2methylpropane chemical reference number cas. Articles of methyl tertbutyl ether are included as well. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Mtbe can enter your body rapidly if you breathe air, drink water, or eat food that contains it. The tba conversion decreases with increasing calcination temperature and alkali metal ion exchange of h.
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